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Binary VLE Data for Low Boiling Components

This section contains the available binary VLE data.  The current focus is on hydrocarbons and low temperature boiling substances including helium, argon, nitrogen, carbon monoxide, carbon dioxide and hydrogen sulfide.

The data is sorted by system and by relative volatility.  For example, data for the methane propane system can be found in Methane Systems while data for Propane n-Butane can be found in the Propane Systems.

 

Helium Systems

• Helium Nitrogen
  • Streett, Chem. Eng. Prog. Symposium Series, 63, 91, 1967, p. 37
  • Davis, Rodwald and Kurata, Ind. Eng. Chem., 55, 11, 1963, p. 36
  • Devaney, Dalton and Meeks, J. Chem. Eng. Data, 8, 4, p. 473, 1963
  • Gonikberg and Fastowsky, Acta Physicochemica URSS, 12, 1, 1940, p. 67
    
    
• Helium Carbon Monoxide
  • Parrish and Steward, J. Chem. Eng. Data, 20, 4, p. 412, 1975
    
    
• Helium Methane
  • Rhodes, devaney and Tully, J. Chem. Eng. Data, 16, 1, p. 19, 1971
  • Devaney, Rodes and Tully,  J. Chem. Eng. Data, 16, 2, p. 158, 1971
  • Heck and Hiza, AICHE J., 13, 3, p. 593, 1967
    
    
• Helium Nitrous Oxide
  • Parrish and Steward, J. Chem. Eng. Data, 20, 4, p. 412, 1975
    
    

Hydrogen Systems

• Hydrogen Nitrogen
  • Yorizane, Yoshimura and Masuoka, Proc. 1st Int. Cryog. Eng. Conf. Heywood Tem. Ind. Pub, p. 57, 1968
  • Maimoni, AICHE J., 7, 3, p. 371, 1961
  • Steckel and Zinn, Zh. Khim. Prom., Moskwa, 16(1939) 24
    
    
• Hydrogen Carbon Monoxide
  • Yorizane, Yoshimura and Masuoka, Proc. 1st Int. Cryog. Eng. Conf. Heywood Tem. Ind. Pub, p. 57, 1968
  • Akers and Eubanks, Adv. Cryo. Eng., 3, p. 275, 1960
  • Verschoyle, Phil. Trans. Roy. Soc. London, A230, p.189, 1931 (not typed yet)
    
    
• Hydrogen Methane
  • Kremer, H., and H. Knapp, Fluid Phase Equil., 11, p. 289, 1983
  • Hong, J. H.,  and R. Kobayashi, J. Chem. Eng. Data, 26, 2, 9. 127, 1981
  • Tsang, C. Y., P. Clancy, J. C. G. Calado, and W. B. Streett, Chem. Eng. Commun., 6, p. 365, 1980
  • Chuang, S., et al, J. Chem. Eng. Data, 21, 4, p. 403, 1976
  • Sagara et. al., J. Chem. Eng. of Japan, 5, 4, p. 339, 1972
  • Yorizane, M. S. et. al., Proc. 1st. Cryog. Int. Eng. Conf., Heywood Tem Ind. Pub., p. 57, 1968
  • Kirk, B.S. and W.T. Ziegler, Adv. Cryo. Eng., 10B, p. 160, 1965
  • Mueller, Leland and Kobayashi, AICHE J,  7, 2, p. 267, 1961 (density only)
  • Benham and Katz, AICHE J., 3, 1, p. 33, 1957
  • Fastowsky, W. and M. Gonikberg, Acta Physicochimica U.R.S.S., XII, 4, p. 484, 1940
  • Freeth T. A. C, and T. T. H. Verschoyle, Proc. Roy. Soc., London, A130, p. 453, 1931
    
    
• Hydrogen Carbon Dioxide
  • 
    
    
• Hydrogen - Ethylene
  • Heintz, A. and W.B. Street, Ber. Bunsenges. Phys. Chem., 87, p. 298, 1983
  • Sagara, Arai and Saito, J. Chem. Eng. Japan, 5, 4, p. 339, 1972
  • Hiza, Heck and Kidnay, Chem. Eng. Prog. Symp. Series, 64, 88, p. 57, 1968
  • Williams, R., B., and D. L. Katz, Ind. Eng, Chem., 46, 12, p. 2512, 1954
    
    
• Hydrogen - Ethane
  • Heintz, A. and W.B. Street, J. Chem. Eng. Data, 27, 4, p. 465, 1982
  • Sagara, Arai and Saito, J. Chem. Eng. Japan, 5, 4, p. 339, 1972
  • Hiza, Heck and Kirk, Adv. Cryo. Eng., 13, p. 343, 1967
  • Cohen, Hipkin and Koppany, Chem. Eng. Prog. Symp. Ser., 63 10, p. 81, 1967
  • Williams, R., B., and D. L. Katz, Ind. Eng. Chem., 46, 12, p. 2512, 1954
  • Levitskaja E. and K. Priannikow, J. Tech. Phys., 9, 20, p. 1849, 1939
    
    
• Hydrogen Propylene
  • Sagara et al, J. Chem. Eng. Japan, 8, 2, p. 98, 1975
  • Williams, R., B., and D. L. Katz, Ind. Eng, Chem., 46, 12, p. 2512, 1954
    
    
• Hydrogen Propane
  • Trust, D., B., and F. Kurata, AICHE J., 17, 1, p. 86, 1971
  • Williams, R., B., and D. L. Katz, Ind. Eng, Chem., 46, 12, p. 2512, 1954
  • Burriss, W. L., et al, Ind. Eng. Chem., 45, 1, p. 210, 1953
    
    
• Hydrogen n-Butane
  • Klink, Cheh and Amick, AICHE J., 21, 6, p. 1142, 1975
  • Nelson and Bonnell, Ind. Eng. Chem., 35, 2, p. 204, 1943
    
    
• Hydrogen n-Hexane
  • Nichols, Reamer and Sage, AICHE J., 3, 2, p. 262
    
    
• Hydrogen n-Heptane
  
  
• Hydrogen Toluene
  • Simnick, Sebastian, Lin and Chao, J. Chem. Eng. Data, 23, 4, p. 339, 1978
    
    
• Hydrogen Tertralin
  • Simnick, Lawson, Lin and Chao, AICHE J., 23, 4, p. 469, 1977
    
    
• Hydrogen Quinoline
  • Sebastian, Simnick, Lin and Chao, J. Chem. Eng. Data, 23, 4, p. 305, 1978
    
    
• Hydrogen bicyclohexyl
  • Sebastian, Yao, Lin, Chao, J. Chem. Eng. Data, 23, 2, p. 167, 1978
    
    
• Hydrogen 1-MethylNaphthalene
  • Sebastian, Simnick, Lin and Chao, J. Chem. Eng. Data, 24, 2, p. 149, 1979
  • Yao, Fluid Phase, Equil., 1, p. 293, 1977-1978
    
    

Nitrogen Systems

• Nitrogen Argon
  • Lewis and Stavely, J. Chem. Thermo, 7, p. 855, 1975
  • Massengill and Miller, J. Chem. Thermo., 5, p. 207, 1973
  • Miller, Kidnay and Hiza, AICHE J., 19, 1, p. 145, 1973
  • Thrope, Trans. Far. Soc., p. 2273, 1968
  • Sprow and Prausnitz, AICHE J., 12, 4, p. 780, 1966
    
    
• Nitrogen - Oxygen
• Din, Trans. Far. Soc., 56, p. 668, 1960
• Crockett, Proc. Roy. Soc. London A, 1956 (NOT ON THE LIST)
• Armstrong, J. Res. Natl. Bur. Stand.,  55, 5, 1955, p. 265
• Dodge and Dunbar, J. Am. Chem. Soc., 49, 1927, p. 591
  
  
• Nitrogen - Ammonia
  
  
• Nitrogen - Carbon Monoxide
  • Sprow and Prausnitz, AICHE J., 12, 4, p. 780, 1966
    
    
• Nitrogen - Nitrous Oxide
  • Zeininger, Chem. Ing. Techn, 44, 9, p. 607, 1972
    
    
• Nitrogen - Hydrogen Sulfide
  • Kalra, Krishnan and Robinson, J. Chem. Eng. Data, 21, 2, p. 222, 1976
  • Besserer and Robinson, J. Chem. Eng. Data, 20, 2, p. 157, 1975
    
    
• Nitrogen - Methane
  • McClure, Lewis, Miller and Staveley, J. Chem. Thermo, 8, p. 785, 1876
  • Kidnay, Miller, Parrish and Hiza, Cryogenics, September, p. 531, 1975
  • Stryjek, Chappelear and Kobayashi, J. Chem. Eng. Data, 19, 4, p. 334, 1974
  • Miller, Kidnay and Hiza, AICHE J., 19, 1, p. 145, 1973
  • Sprow and Prausnitz, AICHE J., 12, 4, p. 780, 1966
  • Cheung and Wang, Ind. Eng. Chem. Fund., 3, 4, p. 355, 1964
    
    
• Nitrogen - Ethylene
  • Grauso, Fredenslund and Mollerup, Fluid Phase Equil., 1, p. 13, 1977
    
    
• Nitrogen - Ethane
  • Grauso, Fredenslund and Mollerup, Fluid Phase Equil., 1, p. 13, 1977
  • Stryjek, Chappelear and Kobayashi, J. Chem. Eng. Data, 19, 4, p. 340, 1974
    
    
• Nitrogen - Propylene
  • Grauso, Fredenslund and Mollerup, Fluid Phase Equil., 1, p. 13, 1977
    
    
• Nitrogen - Propane
  • Grauso, Fredenslund and Mollerup, Fluid Phase Equil., 1, p. 13, 1977
    
    
• Nitrogen - i-Butane
  • Karla, Ng, Miranda and Robinson, J. Chem. Eng. Data, 23, 4, p. 321, 1978
    
    
• Nitrogen - n-Butane
  • Roberts and McKetta, AICHE J., 7, 1, p. 173, 1961
  • Akers, Attwell and Robinson, Ind. Eng. Chem., 46, 12, p. 2539, 1954
    
    
• Nitrogen - i-Pentane
  • Krishnan, Kalra and Robinson, J. Chem. Eng. Data, 22, 3, p. 282, 1977
    
    
• Nitrogen - n-Pentane
  • Kalra, Robinson and Besserer, J. Chem. Eng. Data, 22, 2, p. 215, 1977
    
    
• Nitrogen - n-Hexane
  • Poston and McKetta, J. Chem. Eng. Data, 11, 3, p. 362, 1966
    
    
• Nitrogen - Benzene
  • Miller and Dodge, Ind. Eng. Chem., 32, 3, p. 434, 1940
    
    
• Nitrogen - n-Heptane
  • Akers, Kehn and Kilgore,  Ind. Eng. Chem., 46, 12, p. 2536, 1954
    
    
• Nitrogen - 2,2,5 TrimethylHexane
  • D'Avila, Kaul and Prausnitz, J. Chem. Eng. Data, 21, 4, p. 488, 1976
    
    
• Nitrogen - tertbutylbenzene
  • D'Avila, Kaul and Prausnitz, J. Chem. Eng. Data, 21, 4, p. 488, 1976
    
    
• Nitrogen - n-Decane
  • D'Avila, Kaul and Prausnitz, J. Chem. Eng. Data, 21, 4, p. 488, 1976
  • Azarnoosh and McKetta, J. Chem. Eng. Data, 8, 4, p. 494, 1963
    
    
• Nitrogen - n-Dodecene
  • D'Avila, Kaul and Prausnitz, J. Chem. Eng. Data, 21, 4, p. 488, 1976
    
    

Argon Systems

• Argon - Oxygen
  • Narinskii, Kislorod, 10, 3, p. 9, 1957
  • Clark, Din and Robb, Proc. Roy. Soc. London A, 221, 1147, p. 517, 1954
    
    
• Argon - Methane
  • Christiansen, Fredenslund and Mollerup, Cryogenics, 13, 7, p. 405, 1973
  • Sprow and Prausnitz, AICHE J., 12, 4, p. 780, 1966
  • Cheung and Wang, Ind. Eng. Chem. Fund., 3, 4, p. 355, 1964
    
    
• Argon - Ammonia
  • Michels, Dumoulin and Van Dijk Physica, 27, 9, p. 886, 1961
    

Methane Systems

• Methane Carbon Dioxide
  
  
• Methane Ethylene
  • Miller, R.C., A.J. and Kidnay, and M. J. Hiza, J. Chem. Thermo., 9, p. 167, 1977
  • Sagara et. al., J. Chem. Eng. Japan, 5, 4, p. 339, 1972
  • Hsi et al, 1971 (This reference is suspect.  The author states that meaurements were made, but no experimental data is presented)
    
    
• Methane Ethane
  • Gupta, Gardner, Higarty and Kidnay, J. Chem. Eng. Data, 25, 4, p. 313, 1980
  • Miller, R.C., A.J. and Kidnay, and M. J. Hiza, J. Chem. Thermo., 9, p. 167, 1977
  • Miller and Staveley, Adv. Cryo. Eng., 21, p. 493, 1976
  • Davalos, Anderson, Phelps and Kidnay, J. Chem. Eng. Data, 21, 1, p. 81, 1975
  • Wilson, Adv. Cryo. Eng., 20, p. 164, 1975
  • Wichterle and Kobayashi, J. Chem. Eng. Data, 17, 1, p. 9, 1972
  • Wichterle and Kobayashi, J. Chem. Eng. Data, 17, 1, p. 13, 1972
  • Price and Kobayashi, J. Chem. Eng. Data, 4, 1, p. 40, 1959
  • Price, Ph.D. Dissertation, Rice University, 1957 (We have it, we'll get to it)
    
    
• Methane Propylene
  • Sagara, Mihara, Arai and Saito, J. Chem. Eng. Japan, 8, 2, p. 98, 1975
  • Orbinskij, Blagoj, Semjannikova and Vjunnik, Fiz. Khim. Rastvorov, 233, 1972
    
    
• Methane Propane
  • Calado, Garcia and Staveley, J. Chem. Soc. Far. Trans. I, 70, p. 1445, 1974
  • Wichterle and Kobayashi, J. Chem. Eng. Data, 17, 1, p. 4, 1972
  • Wichterle and Kobayashi, J. Chem. Eng. Data, 17, 1, p. 13, 1972
  • Price and Kobayashi, J. Chem. Eng. Data, 4, 1, p. 40, 1959
  • Reamer, Sage and Lacey, Ind. Eng. Chem., 42, 3, p. 534, 1950
    
    
• Methane i-Butane
  
  
• Methane n-Butane
  
  
• Methane i-Pentane
  
  
• Methane n-Pentane
  
  
• Methane n-Hexane
  
  
• Methane Cyclo-Hexane
  
  
• Methane n-Heptane
  
  
• Methane n-Octane
  
  
• Methane 2,2,5-Trimethyl-Hexane
  
  
• Methane n-Nonane,
  
  
• Methane n-Decane
  
  
• Methane n-Dodecane
  
  
• Methane Benzene
  
  
• Methane Toluene
  
  
• Methane m-Xylene
  
  

Ethylene Systems (recheck)

• Ethylene - Ethane
  • Barclay, Flebbe and Manley, J. Chem. Eng. Data, 27, 32, p. 135, 1982
    
    
• Ethylene - Propylene
  • Kuboto, Inatome, Tanaka and Makita, J. Chem. Eng. Japan, 16, 2, p. 99, 1983
  • Ohgaki, Nakai, Nitta and Katayama, Fluid Phase Equil., 8, p. 113, 1982
  • Bae, Nagahama and Hirata, J. Chem. Eng. Japan, 14, 1, p. 1, 1981
    
    
• Ethylene - Propane
  • Kaminishi and Takahashi, Koatsu Gasu, 20, 9, p. 485, 1983
  • ElShayal and Lu, Can. J. Chem. Eng., 53, p. 83, 1975
    
    
• Ethylene - n-Butane
  • P
    
    
• Ethylene - Benzene
  • P
    
    
• Ethylene - n-Heptane
  • P
    
    
• Ethylene - n-Decane
  • P
    
    

Ethane Systems

• Ethane - Propylene
  • Ohgaki, Nakai, Nitta and Katayama, Fluid Phase Equil., 8, p. 113, 1982
  • Sage and Lacey, Am. Petrol. Inst. Project 37, 1955
  • McKay, Reamer, Sage and Lacey, Ind. Eng. Chem., 43, 9, p. 2112, 1951
    
    
• Ethane - Propane
  • P
    
    
• Ethane - i-Butane
  • D
  • R
  • H
    
    
• Ethane - n-Butane
  • P
    
    

Propylene Systems

• Propylene - Propane
  • M
    
    
• Propylene - 1-Butene
  • Goff, Farrington and Sage, Ind. Eng. Chem.,  42, 4, p. 735, 1950
    
    
• Propylene - i-Butane
  • Gilliland and Sheeline, Ind. Eng. Chem., 32, 1, p. 48, 1940
    
    
• Propylene -
  • P
    
    

Propane Systems

• Propane - i-Butane
  • Hipkin, AICHE J.,  12, 3, p. 484, 1966
    
    
• Propane - n-Butane
  • P
    
    
• Propane - i-Pentane
  • Vaughan and Colllins, Ind. Eng. Chem., 34, 7, p. 885, 1942
    
    
• Propane - n-Pentane
  • P
    
    
• Propane - n-Hexane
  • P
    
    

1,3-Butadiene Systems(check alpha)

• 1,3-Butadiene - n-Butane
  • Laurance and Swift, J. Chem. Eng. Data,  19, 1, p. 61, 1974
    
    

1-Butene Systems(check alpha)

• 1-Butene - 1,3-Butadiene
  • Laurance and Swift, J. Chem. Eng. Data,  19, 1, p. 61, 1974
    
    
• 1-Butene - n-Butane
  • Laurance and Swift, J. Chem. Eng. Data,  19, 1, p. 61, 1974
    
    

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